Graphite
Natural Flake Graphite is an industrial mineral with unique properties primarily due to its structure
- It is a pure form of carbon where flat hexagonal platelets are stacked on each other like a deck of cards, held together by relatively weak intermolecular forces.
- It is a mineral with very anisotropic properties, that is, the partical’s electrical, thermal, physical and chemical properties are different in the plane axis along the layers of platelets than in the vertical axis going through the layers. Like a metal, it has high electrical and thermal conductivity along its planar axis, yet relatively poor going through the layers.
- These weakly bonded layers give graphite its slipperiness or lubricity.
- Paradoxically, graphite is one of the softest minerals, yet stronger per unit weight than steel.
- It's strength increases as its temperature is increased.
- Graphite absorbs energy regardless of the source making it ideal for sports equipment such as tennis racquets, fishing rods, golf clubs, etc.
- It is inert to almost all substances including corrosive chemicals even at elevated temperatures making it ideal for gaskets, packing material, brake and clutch plates, etc.
- Graphite is replacing asbestos in many areas because of the hazards associated with that mineral.
- Graphite can withstand a wide range of temperature from very cold levels to >3000°C in inert and reducing atmospheres and vacuum making it invaluable in many applications ranging from cryogenic to nuclear reactor temperature levels.
- Graphite acts as a neutron moderator, a requirement for thermal nuclear reactors.
- Graphite flake can be exfoliated into thinner and thinner sheets much like expanded vermiculite or popcorn when heated under controlled conditions.
- If exfoliation is taken to the extreme, individual sheets of "graphene" can be formed. These are one-atom thick layers of carbon with properties that rival steel in strength, silicon in quality for integrated circuitry, and copper in electrical conductivity.
Uses of natural graphite (http://en.wikipedia.org/wiki/Graphite)
Natural graphite is mostly consumed for refractories, steelmaking, expanded graphite, brake linings, foundry facings and lubricants. Graphene, which occurs naturally in graphite, has unique physical properties and might be one of the strongest substances known; however, the process of separating it from graphite will require some technological development before it is economically feasible to use it in industrial processes.
Expanded graphite is made by immersing natural flake graphite in a bath of chromic acid, then concentrated sulfuric acid, which forces the crystal lattice planes apart, thus expanding the graphite. The expanded graphite can be used to make graphite foil or used directly as "hot top" compound to insulate molten metal in a ladle or red-hot steel ingots and decrease heat loss, or as firestops fitted around a fire door or in sheet metal collars surrounding plastic pipe (during a fire, the graphite expands and chars to resist fire penetration and spread), or to make high-performance gasket material for high-temperature use. After being made into graphite foil, the foil is machined and assembled into the bipolar plates in fuel cells. The foil is made into heat sinks for laptop computers which keeps them cool while saving weight, and is made into a foil laminate that can be used in valve packings or made into gaskets. Old-style packings are now a minor member of this grouping: fine flake graphite in oils or greases for uses requiring heat resistance. A GAN estimate of current US natural graphite consumption in this end use is 7,500 tonnes.


